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Methemoglobin (MetHb), mixed sample

Immunology & Autoimmune

Co-oximetry MetHbMetHbMethemoglobinMethemoglobin fraction

Review status

Currently under review

Pending specialist review and validation.

What it shows

Methemoglobin is a form of hemoglobin that cannot carry oxygen effectively. The MetHb Mixed test measures the proportion of your total hemoglobin that is in the methemoglobin form using co-oximetry on a mixed blood sample. This helps detect methemoglobinemia, a condition in which methemoglobin increases and reduces oxygen delivery to tissues.

This test is often performed when there is concern for exposure to certain medications or chemicals that can oxidize hemoglobin, or when an inherited enzyme or hemoglobin variant is suspected. It is done on whole blood and is part of a broader co-oximetry assessment that can also characterize other hemoglobin species.

Why it matters

Too much methemoglobin can lead to low oxygen delivery, causing symptoms such as gray or blue skin color, headache, shortness of breath, fatigue, or confusion. Clinicians order this test when they suspect acquired methemoglobinemia from drugs or chemicals, after use of topical anesthetics, during inhaled nitric oxide therapy, in certain critical care settings, or when a hereditary cause is considered.

Knowing your methemoglobin level helps your care team identify a trigger, stop harmful exposures, and decide on treatments. It can guide whether supportive care alone is enough or if specific therapy is needed, and it can help track improvement as the underlying cause is corrected.

Understanding your results

Your clinician will interpret your result together with your symptoms, exam findings, pulse oximetry, and other co-oximetry measurements. A small amount of methemoglobin is expected in everyone. Higher values may suggest an acquired cause, such as a medication or chemical exposure, or less commonly a hereditary enzyme deficiency or hemoglobin variant.

If your level is elevated and you feel unwell, urgent medical care may be needed. Management often includes stopping the trigger, giving supplemental oxygen, and considering specific therapy based on your overall health, including conditions such as G6PD deficiency or anemia, and pregnancy status. Follow-up testing may be used to confirm improvement after treatment or after the exposure has been removed.

Reference ranges

00.02 fraction
All sexes
0 days – 150 years

Reference intervals vary by laboratory, analyzer, methodology, population, and units. The ranges shown here are for education only. Always interpret your results against the reference interval printed on your own lab report.

Factors that could impact Methemoglobin (MetHb), mixed sample

  • Oxidant drugs and chemicals

    Medications and agents such as benzocaine and other topical anesthetics, dapsone, nitrates or nitrites, phenazopyridine, and certain dyes can raise methemoglobin. Tell your clinician about all prescriptions, over-the-counter products, and exposures.

  • Inhaled nitric oxide or extracorporeal support

    Therapies like inhaled nitric oxide and some extracorporeal circuits can increase methemoglobin formation. Levels may be monitored during treatment to guide dosing and safety.

  • Sample and analytical interferences

    Hemolysis, severe lipemia, icterus, or the presence of unusual dyes can affect spectrophotometric co-oximetry. Proper tube selection, prompt analysis, and avoiding contamination improve result accuracy.

  • Inherited conditions

    Deficiency of cytochrome b5 reductase or hemoglobin M variants can cause lifelong elevations. Family history or persistently elevated results without clear exposure may prompt genetic evaluation.

  • Newborns and infants

    Young infants have immature enzyme systems and may be more prone to methemoglobinemia, especially with certain medications or contaminated water sources. Clinicians interpret results in this context.

  • G6PD deficiency and anemia

    G6PD deficiency affects treatment choices and may complicate management. Underlying anemia or cardiorespiratory disease can worsen symptoms at a given methemoglobin level.

2026

References

  1. McGill University Health Centre. (2020, March 18). MetHb Mixed (Task CD 1092138). Laboratory reference ranges.
  2. American College of Medical Toxicology; American Academy of Clinical Toxicology. (2017). Methylene blue for treatment of methemoglobinemia: Position statement.
  3. Wright, R. O., Lewander, W. J., & Woolf, A. D. (1999). Methemoglobinemia: Etiology, pharmacology, and clinical management. Annals of Emergency Medicine, 34(5), 646–656.
  4. Clinical and Laboratory Standards Institute. (2010). Blood gas and pH analysis and related measurements; Approved guideline (CLSI document C46-A2).